The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a perlite, albite, bentonite, polyhalite, aluminum hydroxide and celestite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant 2,6-bi(diethylamino methyl)-4-nonylphenol-chlorobenzene hyamine and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including 1,1,1-trifluoroacetylacetone neodymium, tri(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octene diketone) dysprosium (III), tri(fluoroform sulfimide) ytterbium and lutetium carbonate hydrate rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound cobalt gluconate, nickel citrate and precious metal chemical complex gold potassium chloride and terpyridyl ruthenium chloride hexahydrate in a hydrothermal reaction kettle under the effect of beta-ethoxy dimethyl dodecyl ammonium sulfate used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.