The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: by taking gamma-aluminum oxide, barite, perlite, albite, magnesia spinel and olivinite as carriers, modifying the carriers by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding a surfactant, bidecalkyl dimethyl ammonium chloride, and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on the carriers, compound mineralizers including borax and potassium sulphate, catalytic activated assistant precursors including 4(2, 2, 6, 6, 6-tetramethyl-3, 5-heptanedione) cerium (IV), tri(3-trifluoroacetyl-D-camphor) praseodymium (III), holmium oxalate hydrate and tri(fluoroform sulfimide) ytterbium, and catalytic active core component precursors including manganese lysine, cupric glutamate, diphenol ethylene diamine tungsten compound and dipotassium hexachloroosmium in a hydrothermal reaction kettle under the effect of N-dodecyl dimethyl-N'-trimethyl-2-hydroxypropyl ammonium dichloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.