The invention relates to a method for preparing an ozone heterogeneous oxidized solid catalyst, which belongs to the technical fields of environmental protection and a chemical catalyst. The preparation method comprises the following steps: diatom pure, kyanite, hydrotalcite, alum stone, nitratine and dolostone are taken as carriers, the carriers are subjected to hole-reaming modification through lithium hypochlorite and dis(acetylacetone)beryllium, a surfactant dodecyl dimethyl hydroxyethyl ammonium chloride is added, surface activation treatment is carried out under supersonic wave effect, then the carriers after ultrasonic surface activation are subjected to a hydro-thermal reaction with a composite mineralizer borax and potassium sulfate, a catalytic activity auxiliary agent predecessor tri(hexafluoroacetylacetone)yttrium (III)dehydrate, tricyclopentadiene promethium, tri(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octylene dione)dysprosium (III), tri(trifluoromethanesulfonimide)ytterbium, a catalytic activity central composite predecessor common transition metallorganic compound pyruvate iso-nicotinoylhydrazone vanadium, cobalt gluconate and hexanitro rhodium trisodium, dipotassium hexachloroosmium in a hydro-thermal reaction vessel under effect of an emulsifier dioctadecalkyl ammonium bromide, the reaction products are dried to remove the moisture, in a muffle furnace, and the product is calcinated to obtain the ozone heterogeneous oxidized solid catalyst.