The invention belongs to the technical field of environment protection and chemical catalysts and relates to an ozone heterogeneous oxidation solid catalyst preparation method. The preparation method includes: taking porous mineral materials including medical stone, wollastonite, bentonite, polyhalite, nitratine and dolomite as carriers; subjecting the carriers to lithium hypochlorite and bis(acetylacetone)beryllium broaching modification; adding surfactant octadecyltrimethyl ammonium chloride for surface activation under the action of ultrasonic waves; subjecting the carriers subjected to ultrasonic surface activation to hydrothermal reaction, with a complex mineralizer composed of borax and potassium sulfate, catalytic activity auxiliary agent precursors including isopropyl scandium oxide (III), tris[N,N-bis(trimethylsilane)amine]erbium, thulium trifluoromethanesulfonate (III) and tri(trifluoromethanesulfonimide)ytterbium rare earth metal organic compounds and catalytic activity central component precursors including normal transition metal organic compounds namely titanocene ring substituted salicylic complex and L-aspartic acid molybdenum and precious metal compounds namely gold potassium chloride and trisodium rhodium hexanitrite, in a hydrothermal reactor under the action of nonylphenol biquaternary ammonium salt serving as an emulsifying agent; drying reaction products to remove moisture, and firing in a muffle furnace at a certain temperature to obtain an ozone heterogeneous oxidation solid catalyst.