利索-全球专利检索

  1. 登录
  2. 注册
发明授权
CN107163056B 用于电催化析氧反应的卟啉锌配合物及其制备方法 失效 - 权利终止

用于电催化析氧反应的卟啉锌配合物及其制备方法
摘要：
本发明公开了一种用于电催化析氧反应的卟啉锌配合物及其制备方法，其其分子式为Zn(CNTCPP)，其中Zn为二价离子，CNTCPP为5,10,15,20‑四氰基苯基卟啉配体；配合物结构属于单斜晶系P21/n空间群，晶体的基本结构单元是由不对称单元通过对称操作得到，对称操作码为x，y，z；0.5‑x，0.5+y，0.5‑z；‑x，‑y，‑z；0.5+x，0.5‑y，0.5+z；不对称单元中由一个配体CNTCPP和一个Zn2+组成，晶胞参数为轴长轴角α＝90.00°，β＝100.777(3)°，γ＝90.00°，晶胞体积为Z＝2。本发明的优点在于：1、反应所用溶剂易得、价廉、绿色无污染；2、反应条件简单、反应可快速进行、节约能源、节省时间；3、产率高、配体用量低，节省成本。
摘要（英）：

The invention discloses a zinc porphyrin complex used for electrocatalysis oxygen evolution reaction, and a preparation method thereof. The molecular formula of the zinc porphyrin complex is Zn(CNTCPP), wherein Zn is a divalent ion, CNTCPP is 5,10, 15, 20-tetracyanide phenyl porphyrin ligand; the structure of the zinc porphyrin complex belongs to monoclinic system P2<1>/n space group; the crystal basic structure unit is obtained from an asymmetric unit via symmetry operation; symmetry operation codes are x, y, z; 0.5-x, 0.5+y, 0.5-z; -x, -y, -z; 0.5+x, 0.5-y, 0.5+z; the asymmetric unit is composed of a ligand CNTCPP and Zn<2+>, lattice parameters axial length a=9.7858(3) angstroms, b=9.3797(2) angstroms, c=21.3172(5) angstroms; axial angle alpha=90.00 DEG, beta=100.777(3) DEG, gamma=90.00 DEG; unit cell size V=1922.15(9) angstroms3, Z=2. The advantages are that: 1, the reaction solvent is easily available, cheap, and green, and no pollution is caused; 2, reaction conditions are simple, reaction can be realized quickly, energy is saved, and time is saved; and 3, yield is high, ligand using amount is low, and cost is low.

公开/授权文献
0/0