The invention provides a high-air permeability deoxidizer packaging material and a preparation method thereof, and belongs to the technical field of packaging materials. The problem of poor air permeability of existing deoxidizer packaging materials is solved in the invention. The high-air permeability deoxidizer packaging material comprises a printed film, a food wrapping paper and an air permeable film, the printed film is provided with a plurality of through air permeable holes, the bottom surface of the printed film is compounded on the top surface of the food wrapping paper by an adhesive, the bottom surface of the food wrapping paper is compounded on the top surface of the air permeable film by the adhesive, and a waterproof and oil-resistant layer is arranged between the bottom surface of the food wrapping paper and the adhesive. The top surface of the food wrapping paper is provided with the printed film provided with the air permeable holes, and the bottom surface of the food wrapping paper is provided with the air permeable film, so the entire packaging material has a good air permeability; and the waterproof and oil-resistant layer arranged between the air permeable film and the food wrapping paper has good waterproof and oil-resistant effects.