The invention relates to a silicone oil-free shampoo containing a persimmon extract and a preparation method thereof. The shampoo contains (a) persimmon extract, (b) anionic surfactant, (c) cationic surface active agent, (d) non-ionic surface active agent and/or ampholytic surfactant, (e) cosmetic additive and (f) glycerol. The shampoo is capable of improving the wet carding property and dry carding property of hair and keeping hair bright and smooth.