The present invention relates to an electrode with a multilayer structure and a lithium secondary battery having the same, characterized by comprising: an electrode current collector for transmitting electrons between an external wire and an electrode active material; and three or more electrode compound layers that are consecutively applied onto the electrode current collector, wherein the electrode compound layers respectively include an electrode active material and a conductive material, and the conductive material content of electrode compound layers that are relatively closer to the current collector of adjacent electrode compound layers with reference to the formation direction of the electrode compound layers is higher than the conductive material content of electrode compound layers that are located relatively further from the current collector.