The invention discloses a method for rapidly screening five phenol compounds in toys. The method comprises the following steps: adding a to-be-tested sample into a carrier containing an extraction solvent, applying a high voltage, and forming electrospray to enter ion mobility spectrometry so as to perform real-time online analysis, wherein the five phenol compounds refer to bisphenol A, octyl phenol, 4-tert-butylphenol, 4-methoxyphenol and 4-ethoxyphenol. The method disclosed by the invention has the advantages of being rapid, stable, low in cost, easy and convenient to operate and the like.