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发明公开
CN107629017A 一种[60]富勒烯噁唑衍生物及[60]富勒醇衍生物的合成方法 无效 - 撤回

一种[60]富勒烯噁唑衍生物及[60]富勒醇衍生物的合成方法
摘要：
本发明公开了一种[60]富勒烯噁唑衍生物及[60]富勒醇衍生物的合成方法，属于富勒烯衍生物的合成技术领域。本发明的技术方案要点为：一种FeCl2•4H2O促进的[60]富勒烯噁唑衍生物及[60]富勒醇衍生物的合成方法，具体过程为：以[60]富勒烯和Weinreb酰胺为反应原料，利用内氧化策略，通过FeCl2•4H2O的促进作用发生接力串联反应合成[60]富勒烯噁唑衍生物及[60]富勒醇衍生物。本发明的合成工艺具有底物适用范围广，化学选择性高，原料相对易得且操作简单等特点。
摘要（英）：

The invention discloses a synthesis method of a [60] fullerene oxazole derivative and a [60] fullerol derivative and belongs to the technical field of synthesis of the fullerene derivative. The technical scheme has the key points that the synthesis method of the [60] fullerene oxazole derivative and the [60] fullerol derivative enhanced by FeCl2.4H2O. The synthesis method comprises the specific processes of by adopting [60] fullerene and Weinreb amide as reaction materials, and utilizing an internal oxidation strategy, synthesizing the [60] fullerene oxazole derivative and the [60] fullerol derivative by generating boosting cascade reaction under the enhancing action of the FeCl2.4H2O. The synthesis process disclosed by the invention has the characteristics of wide substrate-application range, high chemical selectivity, relatively-easy obtaining of materials and simple operation and the like.

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