The invention relates to a conductive Polymer oligomer and applications thereof, and belongs to the conductive Polymer preparation technical field; the Pyrroles oligomer is featured in that the weightaverage molecular weight (Mw) is 522-912, the molecular weight distribution coefficient is 1.1-1.3, and 8-14 pyrroles ring oligomers are correspondingly contained. The invention also provides a carbon material/ Pyrroles oligomer compound, wherein the Pyrroles oligomer is deposited on the surface of the carbon material; the Pyrroles oligomer can be applied to an electrochemistry energy storage material; the invention also provides the carbon material/ Pyrroles oligomer compound applications, and the compound can serve as ion battery and super capacitor electrode materials. The prepared Pyrroles oligomer has a higher charge carrier density which facilitates applications thereof in the electrochemistry energy storage field.