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发明公开
CN108586761A 一种锆的三维金属-有机骨架材料、制备方法及水蒸气吸附应用 失效 - 权利终止

一种锆的三维金属-有机骨架材料、制备方法及水蒸气吸附应用
摘要：
一种锆的三维金属-有机骨架材料、制备方法及水蒸气吸附应用，属于晶态材料的技术领域。化学分子式[Zr6O8(TPHB)1.5(HCOO)3(H2O)3]，其中为有机配体4,4',4”,4”',4””,4””'-(苯并菲-2,3,6,7,10,11-六基)六苯甲酸。密封条件下，有机配体H6TPHB与八水氯氧化锆在DMF和甲酸的混合溶液中，经由热反应得到该金属-有机骨架的晶体。此金属-有机骨架具有较大的孔尺寸以及比表面积，并且在水溶液中能保持其骨架结构，可用作水蒸气的吸附材料。
摘要（英）：

The invention discloses a zirconium three-dimensional metal-organic framework material, a preparation method thereof and a water vapor adsorption application, and belongs to the technical field of crystalline materials. A chemical molecular formula is [Zr6O8(TPHB)1.5(HCOO)3(H2O)3], wherein H6TPHB is organic ligand 4,4',4'',4''',4'''',4'''''-(benzophenanthrene-2,3,6,7,10,11-hexyl)hexabenzoic acid.Under the sealed condition, the organic ligand H6TPHB and zirconium oxychloride octahydrate are subjected to a thermal reaction in a mixed solution of DMF and formic acid to obtain a crystal of the metal-organic framework. The metal-organic framework disclosed by the invention has a larger pore size and specific surface area, can maintain the framework structure in an aqueous solution and be usedas an adsorbing material of water vapor.

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