The invention provides novel environment-friendly packing for a mobile bed biofilm method. The novel environment-friendly packing for the mobile bed biofilm method is characterized by comprising an external-layer mesh bag and inner-layer filling microspheres; the inner-layer filling microspheres comprise, by mass, 5-10 parts of carbonized rice husk powder, 5-10 parts of diatomite, 5-10 parts of hydroxy calcium phosphate, 40-60 parts of PVC elastomer, 20-40 parts of polyvinyl alcohol resin, 2-6 parts of stearic acid, 1-5 parts of polyacrylamide and 10-20 parts of foaming agent; the external-layer mesh bag is thermoplastic resin and adheres to the surfaces of the inner-layer filling microspheres through thermal treatment. The novel environment-friendly packing for the mobile bed biofilm method is simple in structure, can lower the production cost, and is environmentally friendly, easy to degrade, large in hanging film amount, and high in sewage treatment efficiency.