The invention discloses a glazed microfiber silicone rubber synthetic leather, which is prepared by laminating a super bright glazed layer, a liquid silicone rubber layer, and a microfiber fabric in sequence. The liquid silicone rubber layer is composed of following raw materials in parts by weight: 50 to 80 parts of basic rubber of silicone rubber, 3 to 5 parts of silane coupling agent, 5 to 10 parts of hydrogen containing silicone oil, 0.1 to 0.5 part of platinum catalyst, 5 to 20 parts of color paste pigment, and 0.02 to 0.1 part of inhibitor. The invention also discloses a manufacturing technology of the glazed microfiber silicone rubber synthetic leather. Liquid silicone rubber with high hardness and elongation rate is taken as the basic material to prepare the silicone rubber synthetic leather; in order to guarantee the mechanical performance of the silicone rubber synthetic leather, hydrogen containing silicone oil with a high hydrogen content is taken as the crosslinking agent,and the obtained glazed microfiber silicone rubber synthetic leather has an excellent bending resistant performance. A layer of colored silicone rubber is painted on the microfiber surface so as to fully fill the gaps in the microfiber surface, then the microfiber and transparent silica gel are adhered together, and the mirror effect is very obvious.