The invention discloses a preparation method for steel fiber-rice fiber reinforced expanded perlite luminescent concrete. The preparation method comprises the following steps: putting the natural coarse aggregate broken stone, the fine aggregate medium sand, recycled coarse aggregate and a ceramic powder admixture into a mixer for dry mixing; then adding cement, fly ash, slag powder, expanded perlite, long-afterglow strontium aluminate luminescent powder and modified straw fiber, and carrying out dry mixing; adding tap water doped by a naphthalene-based high-efficiency water reducing agent andcarrying out stirring; evenly sprinkling the obtained mixture into steel fibers and carrying out uniform mixing; charging the obtained concrete mixture, inserting and stamping the concrete mixture along the inner wall of a test mold by using a spatula; after a test piece is formed, covering the surface of the test piece with a preservative film; and after removal from the mold, placing the test piece into a standard curing box for curing. The long-afterglow strontium aluminate luminescent powder is prepared through a combination of a precipitation synthesis method and a high-temperature solidphase synthesis method; the long-afterglow luminescent powder is a photoluminescent material; and after blending of the long-afterglow luminescent powder into the concrete, the concrete is allowed toabsorb and store sunlight during daytime and then slowly release energy stored by the luminescent powder at night.