The invention belongs to the field of lithium sulfide battery positive electrode material and specifically relates to a preparation method and application of a lithium sulfide battery positive electrode. The lithium sulfide battery positive electrode comprise a positive electrode active material, a stabilizer, a conductive agent and a bind, wherein that positive electrode active material is insoluble sulfur. The stabilizer is a compound capable of forming a common electron pair with sulfur atoms at both ends of the positive electrode active material, preferably at least one of a halogen, an organic halide and a thiazole compound. The positive electrode active material of the invention greatly reduces the dissolution of the polysulfide, and the insoluble sulfur stabilizer used together caneffectively restrain the generation of dead sulfur and the shuttle effect in the electrode reaction process. The positive electrode assembled lithium sulfide battery provided by the invention has highfirst discharge specific capacity and good cycle performance. In addition, the preparation method of the sulfide positive electrode provided by the invention is low in cost, simple in operation and easy to realize large-scale commercial manufacture.