The invention discloses an organic and inorganic compound membrane with light selective adsorbing and anti-ageing functions. The organic and inorganic compound membrane comprises the following components in parts by weight: 45-99.8 parts of a polymer, 0.4-40 parts of multilayered structure compound particles, 0-45 parts of a plasticizer or a softener and 0-10 parts of an auxiliary agent. The invention discloses a preparation method of the organic and inorganic compound membrane. The organic and inorganic compound membrane can be widely applied to the fields of building, space flight and aviation, electronic information, rubber, plastics and the like for preparing functional compound glass and transparent apparatuses. The organic and inorganic compound membrane with light selective adsorbing and anti-ageing functions is simple in preparation method and is easily produced on a large scale.