The invention discloses a method for synthesizing anisole by catalyzing phenol and methanol. According to the method, a fixed bed reactor is adopted, and a metal-non metal compound oxide loaded with active components KF, CsF, NaF or CaF is used as a catalyst. The metal oxide is oxides of Al, Cu, Zn, Co and Cr, the non-metal oxide is white carbon black, the phenol conversion rate is high, the selectivity of the anisole is high, the preparation process of the catalyst is simple, the cost is low, the stability is high, the service life is long, and the application requirements of the industrial catalyst are met.