The invention discloses a phosphorus-doped self-cleaning double silver LOW-E glass, which comprises a first glass substrate and a second glass substrate, wherein a phosphorus titanium dioxide composite film layer is compounded on the first side surface of the first glass substrate, nine film layers are sequentially compounded on the second side surface of the first glass substrate from bottom to top, the first film layer is a Si3N4 layer, the second layer is an AZO layer, the third layer is an Ag layer, the fourth layer is a NiCr layer, the fifth layer is a ZnSnO4 layer, the sixth layer is anAZO layer, the seventh layer is an Ag layer, the eighth layer is a NiCr layer, the ninth layer is a Si3N4 layer, and a sealed hollow cavity is arranged between the ninth layer Si3N4 layer and the second glass substrate. According to the present invention, the self-cleaning ability of the TiO2 self-cleaning film can be further improved through the phosphorus in the phosphorus-doped TiO2 self-cleaning film so as to reduce the frequency of the cleaning; and through various film layers with different functions, the transmittance of infrared rays can be sequentially reduced or infrared rays with different wavebands are reflected so as to reduce the transmittance of infrared light, such that the purposes of high transmittance of visible light and energy saving can be achieved.