The invention provides a thermoelectric power generation seat. The thermoelectric power generation seat comprises a seat main body, a thermoelectric power generation unit, a storage battery and an electronic device. The thermoelectric power generation unit is fixedly installed on the seat main body, the storage battery is electrically connected with the thermoelectric power generation unit, and the electronic device is electrically connected with the storage battery. Two different thermally responsive material conductors are arranged to from a closed loop and are connected with the storage battery, the generation of the thermally responsive materials is achieved by combining the temperature difference when a person sits on the seat by employing the Seebeck effect to charge the storage battery, at the same time, the storage battery is connected with electronic devices through a joint such as an electric lamp, a mobile phone, an electric fan lamp and a laptop lamp. The thermoelectric power generation seat is environmental friendly, easy and easy to operate, can store the electric quantity, can be directly used, is convenient to office, can be applied to rail traffic and an aircraft,and is convenient for passengers to charge.