The invention discloses prestressed concrete pavement suitable for a flat curve road section and a construction method thereof. The prestressed concrete pavement includes cement concrete, V-shaped prestressed tendons, reinforcing rebars, an anchorage zone, and a sliding layer, wherein bi-directional prestressed tendons are bent into a V shape and distributed in the cement concrete in the road driving direction, and the reinforcing rebars are arranged in blank areas of the prestressed reinforcement at both ends of the prestressed pavement; the V-shaped prestressing tendons adopt two-times tension, according to a symmetrical tension principle, one-direction prestressing tendons are tensioned successively from one end of the pavement to the other end, and then reverse prestressing tendons aretensioned successively. The prestressed concrete pavement can be used for paving the pavement of a straight road section, has the advantages of ordinary inclined prestressed concrete pavement, and can further adapt to a road line shape of the flat curve road section; and the arrangement mode of the V-shaped prestressed tendons reduces the area of a zone where the prestressed tendons cannot be arranged at both ends of the ordinary inclined prestressed concrete pavement, the pavement stress state is optimized; and fixed form prestressed tendons are convenient for construction, installation andpositioning.