The invention provides a die of a multi-hook-face modeling lining mould for a concrete structure and a making method of the die. The die comprises a plurality of fiber reinforced plastic hollow die blocks which are spliced together, the interiors of the fiber reinforced plastic hollow die blocks are communicated with one another to form a casting cavity used for casting the multi-hook-face modeling lining mould, the side wall of each fiber reinforced plastic hollow die block comprises an outer surface layer, an inner base layer and a core layer arranged between the outer surface layer and theinner base layer, and a framework is buried in each core layer. By means of the die, the problems that it is hard to machine metal lining moulds traditionally, and the efficiency of machining the lining moulds is low are solved.