The invention relates to new type super long afterglow luminescent material and its manufacturing method. The material includes the phosphor which is made up of aMS.bM3 (PO4)2.cMSiO2.dMOfAl2O3.xRO.yTR2O3.zMnO. The M can be calcium, magnesium, barium, strontium, zinc or their combination; the R can be europium, samarium, ytterbium, praseodymium, neodymium or their component; the TR can be lanthanum, yttrium, neodymium, dysprosium, erbium, thulium, cerium, holmium or their component; the a, b, c, d, f, x, y, z are mole numbers. And it has superior water and temperature resistances.