The utility model discloses an energy-saving and environment-friendly door and window with a generating function. The energy-saving and environment-friendly door and window comprises a sash and a glass leaf, wherein the glass leaf consists of an amorphous silicon film solar cell panel of which the outer layer has a light-transmitting effect and inner layer glass; periphery of the amorphous silicon film solar cell panel and the periphery of the inner layer glass are fixed by an aluminum partition strip of a molecular sieve; the inner layer glass is single-layer glass or dual-layer hollow glass or multi-layer hollow glass; a terminal box groove is formed in an upper frame, a lower frame, a left frame or a right frame; a terminal box of the amorphous silicon film solar cell panel is arranged in the terminal box groove; an outgoing line hole which is communicated with the terminal box groove is formed in the upper frame, the lower frame, the left frame or the right frame; and an outgoing line of the terminal box is led out of an outgoing line hole in the sash. By the energy-saving and environment-friendly door and window, the aims of fire and electricity conservation, energy conservation and environment friendliness are fulfilled, the effects of indoor sunscreen and temperature reduction are achieved, and the energy consumption of air conditioners is reduced.