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发明公开
EP0001873A1 Method of producing polyisoprenoid compounds by carbon-carbon bond formation 失效
一种用于通过形成碳 - 碳键制备Polyisoprenoideverbindungen过程。

Method of producing polyisoprenoid compounds by carbon-carbon bond formation
摘要：
A polyisoprenoid compound is prepared by reacting a compound R CH 2 Y wherein Y is lower alkylsulfonyl or arylsulfonyl, and R 1 is isoprenoid or polyisoprenoid, with a XCH 2 R 2 compound wherein X is halogen and R 2 has the same meaning as R', in a polar solvent and in the presence of sodium hydride, potassium hydride, sodium tertiary-alkoxide, potassium tertiary-alkoxide, sodium amide or potassium amide, to obtain a compound
which, in turn, is subjected to a reductive desulfonylation of the group Y, whereby a compound R 1 CH 2 CH 2 R 2 is obtained.
摘要（中）：

聚类异戊二烯化合物是通过使一化合物R制备<1> CH2Y worin Y是低级烷基磺酰基或芳基磺酰基，并且R <1>是类异戊二烯或聚类异戊二烯，具有XCH2R <2>化合物worin X是卤素，R <2>具有 相同的含义为R <1>，在极性溶剂中，在氢化钠，氢化钾，钠叔醇盐，钾醇盐叔胺，氨基钠或氨基钾的存在下，得到的化合物，这反过来 ，进行与基团Y的还原脱磺酰，由此化合物R <1> CH 2 CH 2 <2>中获得。

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