发明公开
- 专利标题: Photographic products and processes as well as color providing compounds
- 专利标题(中): 摄影产品和方法作为颜色提供化合物
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申请号: EP85201350申请日: 1985-08-23
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公开(公告)号: EP0173404A3公开(公告)日: 1986-06-11
- 发明人: Simon, Myron S. , Waller, David P.
- 申请人: POLAROID CORPORATION
- 专利权人: POLAROID CORPORATION
- 当前专利权人: POLAROID CORPORATION
- 优先权: US644915 19840827
- 主分类号: G03C05/54
- IPC分类号: G03C05/54 ; C09B01/40 ; C09B01/28
摘要:
Photographic products and processes for the imagewise generation of a dye from a color shifted dye precursor of a preformed image dye, said precursor having at least one
group, wherein R is hydrogen, alkyl, provided that the a-carbon does not have a hydrogen atom attached thereto, aryl such as phenyl or substituted phenyl, e.g. p-nitrophenyl, or heterocyclic such as pyridine; R 1 -R 6 are hydrogen, alkyl, preferably having from 1 to 6 carbon atoms, or aryl; n is 0 or 1; and T is a moiety containing a thiazolidin-2-yl group which upon silver-assisted cleavage of said thiazolidin-2-yl group results in the formation of a
group, which may be protonated under the reaction conditions, followed by cleavage of said
cleavage is anchimerically assisted or accelerated by said
to provide after protonation, an
group in a dye chromophore. In a preferred embodiment the precursor is a substantially colorless compound.
group, wherein R is hydrogen, alkyl, provided that the a-carbon does not have a hydrogen atom attached thereto, aryl such as phenyl or substituted phenyl, e.g. p-nitrophenyl, or heterocyclic such as pyridine; R 1 -R 6 are hydrogen, alkyl, preferably having from 1 to 6 carbon atoms, or aryl; n is 0 or 1; and T is a moiety containing a thiazolidin-2-yl group which upon silver-assisted cleavage of said thiazolidin-2-yl group results in the formation of a
group, which may be protonated under the reaction conditions, followed by cleavage of said
cleavage is anchimerically assisted or accelerated by said
to provide after protonation, an
group in a dye chromophore. In a preferred embodiment the precursor is a substantially colorless compound.
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