发明授权
EP0203152B1 METHYLSUBSTITUIERTE BICYCLO AD2.2.1 BDHEPTAN-NITRILE, VERFAHREN ZUR HERSTELLUNG DIESER NITRILE UND DEREN VERWENDUNG ALS RIECHSTOFFE
失效
甲基取代的双酚A AD2.2.1 BDHEPTANE NITRILES,这些硝酸盐的生产方法及其用途
- 专利标题: METHYLSUBSTITUIERTE BICYCLO AD2.2.1 BDHEPTAN-NITRILE, VERFAHREN ZUR HERSTELLUNG DIESER NITRILE UND DEREN VERWENDUNG ALS RIECHSTOFFE
- 专利标题(英): Methyl substituted bicyclo ad2.2.1 bdheptane nitriles, process for production of these nitriles and their use as scents
- 专利标题(中): 甲基取代的双酚A AD2.2.1 BDHEPTANE NITRILES,这些硝酸盐的生产方法及其用途
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申请号: EP85906037.8申请日: 1985-11-27
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公开(公告)号: EP0203152B1公开(公告)日: 1988-06-22
- 发明人: BRUNKE, Ernst-Joachim , STRUWE, Hartmut
- 申请人: Dragoco Gerberding & Co. GmbH
- 申请人地址: Dragocostrasse 1 D-37603 Holzminden DE
- 专利权人: Dragoco Gerberding & Co. GmbH
- 当前专利权人: Dragoco Gerberding & Co. GmbH
- 当前专利权人地址: Dragocostrasse 1 D-37603 Holzminden DE
- 代理机构: Eikenberg & Brümmerstedt Patentanwälte
- 优先权: DE3443536 19841129
- 国际公布: WO8603196 19860605
- 主分类号: C07C121/46
- IPC分类号: C07C121/46 ; C07C120/00 ; C11B9/00 ; A61K7/46
摘要:
Methyl substituted bicyclo AD2.2.1 BDheptan nitriles of the general formula (A), wherein the methyl group occupies the position C-4 or C-5, the residue R1 is at C-2 and the nitrile group is at C-3 or alternately the residue R1 is at C-3 and the nitrile group is at C-2, single linking exists between C-5 and C-6, and the sinuous lines represent stereoisomer forms, are new and may be used advantageously as scents, respectively as components of perfume oils for cosmetics or consumer goods. Their production in a preferred mode is effected by first obtaining from an aldehyde of formula (6) resp. (7) the corresponding aldoxine (10) resp. (11), and then obtaining the corresponding nitrile (12) resp. (13) by elimination of water.
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