发明公开
- 专利标题: Wax isomerization catalyst and its production
- 专利标题(中): WAX异构催化剂及其生产
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申请号: EP88311980.2申请日: 1988-12-16
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公开(公告)号: EP0321300A3公开(公告)日: 1989-08-30
- 发明人: Cody, Ian Alfred , Davis, Stephen Mark , Hamner, Glen Porter , Sawyer, Willard Hall
- 申请人: EXXON RESEARCH AND ENGINEERING COMPANY
- 申请人地址: P.O.Box 390, 180 Park Avenue Florham Park, New Jersey 07932-0390 US
- 专利权人: EXXON RESEARCH AND ENGINEERING COMPANY
- 当前专利权人: EXXON RESEARCH AND ENGINEERING COMPANY
- 当前专利权人地址: P.O.Box 390, 180 Park Avenue Florham Park, New Jersey 07932-0390 US
- 代理机构: Somers, Harold Arnold
- 优先权: US134795 19871218
- 主分类号: B01J23/40
- IPC分类号: B01J23/40 ; C10G45/62
摘要:
A wax isomerization catalyst is described which comprises a Group VIII hydrogenation metal component on fluorided alumina-containing alumina. The catalyst has a surface nitrogen content N/Al ratio of 0.01 or less, by X-ray photoelectron spectroscopy, a bulk fluorine content of 2 to 10 wt%, a surface fluorine content defined as the amount of fluorine in a layer extending from the outer surface to a depth of 0.254 mm of less than 3 wt%, the surface fluoride concentration being less than the bulk fluoride concentration, and an aluminum fluoride hydroxide hydrate peak height of 60 or less determined as the relative amount of hydrate represented by a peak in the X-ray diffraction (XRD) pattern of 2ϑ = 0.566 nm when a hydrate level of 100 corresponds to the XRD peak height exhibited by a standard material consisting of 0.6 wt% Pt 150 m²/g gamma-alumina containing 7.2 wt% F made in a specified way. A method for producing the slack wax isomerisation catalyst is also described and involves treating a Group VIII metal-loaded support with a fluorine source under specified conditions, and heating the fluorided support to a specified final temperature range over a specified time.
公开/授权文献
- EP0321300B1 Wax isomerization catalyst and its production 公开/授权日:1992-07-29
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