发明公开
EP0324190A2 Process for the production of 4,4'-diamino-dicyclohexylmethane with a low trans-trans isomer content by the catalytic hydrogenation of 4,4'-diaminodiphenylmethane
失效
一种用于在具有由4,4'-二氨基二苯基甲烷的催化氢化低反式反式异构体含量生产的4,4'-二氨基过程。
- 专利标题: Process for the production of 4,4'-diamino-dicyclohexylmethane with a low trans-trans isomer content by the catalytic hydrogenation of 4,4'-diaminodiphenylmethane
- 专利标题(中): 一种用于在具有由4,4'-二氨基二苯基甲烷的催化氢化低反式反式异构体含量生产的4,4'-二氨基过程。
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申请号: EP88121923.2申请日: 1988-12-31
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公开(公告)号: EP0324190A2公开(公告)日: 1989-07-19
- 发明人: Schmelzer, Hans-Georg , Allen, Gary F. , Bub, Günther, Dr. , Otte, Werner, Dr.
- 申请人: HÜLS AKTIENGESELLSCHAFT , MILES INC.
- 申请人地址: D-45764 Marl DE
- 专利权人: HÜLS AKTIENGESELLSCHAFT,MILES INC.
- 当前专利权人: HÜLS AKTIENGESELLSCHAFT,MILES INC.
- 当前专利权人地址: D-45764 Marl DE
- 代理机构: Steil, Hanna, Dipl.-Chem.
- 优先权: US143884 19880114
- 主分类号: C07C209/72
- IPC分类号: C07C209/72 ; C07C211/35
摘要:
The present invention is directed to a process for the catalytic hydrogenation of a starting material containing 4,4′-diamino-diphenylmethane (4,4′-MDA) or its mixtures with 2,4′-diamino-diphenylmethane, 2,2′-diamino-diphenylmethane and/or higher ring compounds of the diphenylmethane series to a hydrogenation product having a trans-trans isomer content of 4,4′-diamino-dicyclohexylmethane (4,4′-HMDA) of about 15 to 40 weight percent, based on the diamine content of the hydrogenated product, by continuously hydrogenating in at least one fixed bed reactor at a temperature of about 100 to 190°C and a pressure of about 50 to 350 bar in the presence of a ruthenium catalyst on a catalyst support having a BET surface area of about 70 to 280 m²/g and an average pore diameter d p of about 10 to 320 Å, the catalyst being prepared by impregnating the catalyst support to a penetration depth of at least about 50 µm with a soluble ruthenium compound in an amount sufficient to provide a catalyst containing about 0.1 to 5 weight percent ruthenium and subsequently reducing the soluble ruthenium compound to ruthenium.
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