发明公开
EP0352996A2 Process for preparing superconductors 失效
Verfahren zur Herstellung von Supraleitern。

Process for preparing superconductors
摘要:
Bi-Pb-Sr-Ca-Cu-O system and Tl-Pb-Ba-Ca-Cu-O system superconductor having a high Tc phase (about 110 K and about 125 K, respectively, or more) in a high proportion are obtained by adding a calcium compound which forms CaO and a liquid phase at a temperature for firing the superconductors, e.g., Ca₂PbO x (x = 3 or 4); or by starting from a composition represented by the formula: Bi₂Pb (n-1)/2 Sr₂Ca n Cu n+1 O b′ , or
Tℓ₂Pb (n-1)/2 Ba₂Ca n Cu n+1 O b where 2 ≦ n ≦ 10, 9 ≦ b ≦ 40.5, i.e., at a ratio of Ca:Pb = 2:1.
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