发明公开
EP0446801A3 Solid catalyst component for use in polymerization of alpha-olefins
失效
用于ALPHA-OLEFINS聚合的固体催化剂组分
- 专利标题: Solid catalyst component for use in polymerization of alpha-olefins
- 专利标题(中): 用于ALPHA-OLEFINS聚合的固体催化剂组分
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申请号: EP91103566.5申请日: 1991-03-08
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公开(公告)号: EP0446801A3公开(公告)日: 1992-04-22
- 发明人: Sasaki, Toshio , Ebara, Takeshi , Kawai, Kiyoshi
- 申请人: SUMITOMO CHEMICAL COMPANY, LIMITED
- 申请人地址: 5-33, Kitahama 4-chome Chuo-ku Osaka JP
- 专利权人: SUMITOMO CHEMICAL COMPANY, LIMITED
- 当前专利权人: SUMITOMO CHEMICAL COMPANY, LIMITED
- 当前专利权人地址: 5-33, Kitahama 4-chome Chuo-ku Osaka JP
- 代理机构: VOSSIUS & PARTNER
- 优先权: JP64725/90 19900314
- 主分类号: C08F4/656
- IPC分类号: C08F4/656 ; C08F10/00
摘要:
A solid-catalyst component for use in the polymerization of α-olefins obtained by
reducing a titanium compound represented by the following general formula:
Ti(OR¹) n x 4-n
wherein R¹ represents a hydrocarbon group having 1 to 20 carbon atoms, X represents a halogen atom and n represents a number satisfying 0
treating the solid product with an ester compound,
treating the ester-treated solid product with a mixture of an ether compound and titanium tetrachloride or with a mixture of an ether compound, titanium tetrachloride and an ester compound to obtain a trivalent titanium compound-containing solid catalyst precursor, and
treating the solid catalyst precursor with a small quantity of an olefin in the presence of an organoaluminum compound to obtain a solid catalyst component for use in the polymerization of α-olefins.
reducing a titanium compound represented by the following general formula:
Ti(OR¹) n x 4-n
wherein R¹ represents a hydrocarbon group having 1 to 20 carbon atoms, X represents a halogen atom and n represents a number satisfying 0
treating the solid product with an ester compound,
treating the ester-treated solid product with a mixture of an ether compound and titanium tetrachloride or with a mixture of an ether compound, titanium tetrachloride and an ester compound to obtain a trivalent titanium compound-containing solid catalyst precursor, and
treating the solid catalyst precursor with a small quantity of an olefin in the presence of an organoaluminum compound to obtain a solid catalyst component for use in the polymerization of α-olefins.
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