发明公开
- 专利标题: Diisocyanates, diurethanes and diureides from dehydroabietic acid
- 专利标题(中): 脱乙酰壳多糖的脱水剂,脱水剂和脱水剂
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申请号: EP92670001.4申请日: 1992-02-11
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公开(公告)号: EP0505316A3公开(公告)日: 1992-11-25
- 发明人: Carvalheiro, Bárbara Manuela Silva Gigante , Lobo, Ana Maria Felix Trindade , Prabhakar, Alberto Sundaresan , Curto, Maria Joao Marcelo
- 申请人: INSTITUTO NACIONAL DE ENGENHARIA E TECNOLOGIA INDUSTRIAL (INETI)
- 申请人地址: Azinhaga dos Lameiros a Estrada do Paco do Lumiar P-1699 Lisboa Codex PT
- 专利权人: INSTITUTO NACIONAL DE ENGENHARIA E TECNOLOGIA INDUSTRIAL (INETI)
- 当前专利权人: INSTITUTO NACIONAL DE ENGENHARIA E TECNOLOGIA INDUSTRIAL (INETI)
- 当前专利权人地址: Azinhaga dos Lameiros a Estrada do Paco do Lumiar P-1699 Lisboa Codex PT
- 代理机构: Arantes e Oliveira, Joao de
- 优先权: PT96748 19910211
- 主分类号: C07C265/12
- IPC分类号: C07C265/12 ; C07C271/30 ; C07C275/42
摘要:
New compounds having the general formula (I)
where R₁ represents an isocyanate, urethane ou ureide group and R₂ represens a carboxilic acid, salt, ester or amine group, and processes for producing them from dehydroabietic acid (II), comprising nitration followed by reduction or catalytic hydrogenation followed by carbonylation to produce a diisocyanate which reacts with an alcohol or with an amine to afford, respectively, a diurethane or a diureide. The invention compounds may be useful as industrial monomers for polymer production and the polymers and copolymers prepared from these resin acids derivatives are expected to show improved physical properties when compared with those of commercial polymers where such derivatives are not included.
where R₁ represents an isocyanate, urethane ou ureide group and R₂ represens a carboxilic acid, salt, ester or amine group, and processes for producing them from dehydroabietic acid (II), comprising nitration followed by reduction or catalytic hydrogenation followed by carbonylation to produce a diisocyanate which reacts with an alcohol or with an amine to afford, respectively, a diurethane or a diureide. The invention compounds may be useful as industrial monomers for polymer production and the polymers and copolymers prepared from these resin acids derivatives are expected to show improved physical properties when compared with those of commercial polymers where such derivatives are not included.
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