发明公开
- 专利标题: Catalyst component for the polymerisation of olefins and process for preparing olefin polymers using same
- 专利标题(中): 催化剂组分的烯烃聚合并使用相同的烯烃聚合方法。
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申请号: EP93307161.5申请日: 1993-09-10
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公开(公告)号: EP0587440A3公开(公告)日: 1995-03-08
- 发明人: Tajima, Yoshio , Seki, Takashi , Mori, Satoshi , Aida, Fuyuki , Matsuura, Kazuo , Kataoka, Naoki
- 申请人: NIPPON OIL COMPANY, LIMITED
- 申请人地址: 3-12, 1-chome, Nishi-Shimbashi Minato-ku Tokyo JP
- 专利权人: NIPPON OIL COMPANY, LIMITED
- 当前专利权人: NIPPON OIL COMPANY, LIMITED
- 当前专利权人地址: 3-12, 1-chome, Nishi-Shimbashi Minato-ku Tokyo JP
- 代理机构: Cropp, John Anthony David
- 优先权: JP283394/92 19920910; JP360607/92 19921228; JP361970/92 19921228
- 主分类号: C08F4/655
- IPC分类号: C08F4/655 ; C08F10/00
摘要:
A catalyst component for use in the polymerization or copolymerization of olefin(s) is obtained by contacting the following components (1) to (4) with one another:
(1) a compound of the general formula Me¹R¹p(OR²)qX¹4-p-q where R¹ is a hydrocarbon radical having 1 to 24 carbon atoms, X¹ is a halogen atom, Me¹ is Zr, Ti or Hf, and n is 0 ≦ n ≦ 4; (2) a compound of the general formula Me²R³m(OR⁴)nX²z-m-n where R² is a hydrocarbon radical having 1 to 24 carbon atoms, X² is a halogen atom, Me² is an element from Groups I to III in the Periodic Table, z is the valence of Me² and m is 0 ≦ m ≦ z; (3) an organocyclic compound having two or more conjugated double bonds; and (4) a modified organoaluminum compound containing Al-O-Al bond and with at least one branched-chain alkyl group being attached to aluminum atom.
(1) a compound of the general formula Me¹R¹p(OR²)qX¹4-p-q where R¹ is a hydrocarbon radical having 1 to 24 carbon atoms, X¹ is a halogen atom, Me¹ is Zr, Ti or Hf, and n is 0 ≦ n ≦ 4; (2) a compound of the general formula Me²R³m(OR⁴)nX²z-m-n where R² is a hydrocarbon radical having 1 to 24 carbon atoms, X² is a halogen atom, Me² is an element from Groups I to III in the Periodic Table, z is the valence of Me² and m is 0 ≦ m ≦ z; (3) an organocyclic compound having two or more conjugated double bonds; and (4) a modified organoaluminum compound containing Al-O-Al bond and with at least one branched-chain alkyl group being attached to aluminum atom.
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