发明授权
- 专利标题: PRODUCTION OF AN ETHANOL SOLUTION OF ETHYL OR BUTYL HALF-ESTER OF A COPOLYMER
- 专利标题(中): 制备将丁基或半酯共聚物的乙醇溶液
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申请号: EP93906008.3申请日: 1993-02-18
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公开(公告)号: EP0631600B1公开(公告)日: 1997-06-25
- 发明人: ZAMORA, John, N. , CARLIN, Alan, J. , TAZI, Mohammed
- 申请人: ISP INVESTMENTS INC.
- 申请人地址: 818 Washington Street Wilmington, Delaware 19801 US
- 专利权人: ISP INVESTMENTS INC.
- 当前专利权人: ISP INVESTMENTS INC.
- 当前专利权人地址: 818 Washington Street Wilmington, Delaware 19801 US
- 代理机构: Ford, Michael Frederick
- 优先权: US852425 19920316
- 国际公布: WO9319126 19930930
- 主分类号: C08L31/00
- IPC分类号: C08L31/00 ; C08F2/00
摘要:
A process for the production of an ethanol solution of an ethyl or butyl alkyl half-ester copolymer of maleic anhydride and an alkyl vinyl ether which comprises: (a) copolymerizing the monomers in acetone as solvent by simultaneously feeding molten maleic anhydride, a molar excess of methyl vinyl ether, and a solution of a free radical initiator in acetone, into a reactor precharged with acetone, at about 68-85 °C, preferably 70-80 °C; (b) esterifying the acetone solution of said copolymer with ethanol or butanol; and (c) solvent exchanging ethanol for acetone by continuously injecting vapors of ethanol at about 85-95°C into said copolymer solution while simultaneously distilling out acetone therefrom at atmospheric pressure.
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