发明授权
EP0631600B1 PRODUCTION OF AN ETHANOL SOLUTION OF ETHYL OR BUTYL HALF-ESTER OF A COPOLYMER 失效
制备将丁基或半酯共聚物的乙醇溶液

PRODUCTION OF AN ETHANOL SOLUTION OF ETHYL OR BUTYL HALF-ESTER OF A COPOLYMER
摘要:
A process for the production of an ethanol solution of an ethyl or butyl alkyl half-ester copolymer of maleic anhydride and an alkyl vinyl ether which comprises: (a) copolymerizing the monomers in acetone as solvent by simultaneously feeding molten maleic anhydride, a molar excess of methyl vinyl ether, and a solution of a free radical initiator in acetone, into a reactor precharged with acetone, at about 68-85 °C, preferably 70-80 °C; (b) esterifying the acetone solution of said copolymer with ethanol or butanol; and (c) solvent exchanging ethanol for acetone by continuously injecting vapors of ethanol at about 85-95°C into said copolymer solution while simultaneously distilling out acetone therefrom at atmospheric pressure.
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