发明公开
- 专利标题： Use of supported palladium, catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide
- 专利标题（中）： 生产从叔丁基过氧化氢叔丁醇的使用负载钯催化剂。
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申请号： EP94308293.3申请日： 1994-11-10
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公开(公告)号： EP0653401A1公开(公告)日： 1995-05-17
- 发明人: Sanderson, John Ronald , Knifton, John Frederick , Duranleau, Roger George
- 申请人： TEXACO DEVELOPMENT CORPORATION
- 申请人地址： 2000 Westchester Avenue White Plains, New York 10650 US
- 专利权人： TEXACO DEVELOPMENT CORPORATION
- 当前专利权人： TEXACO DEVELOPMENT CORPORATION
- 当前专利权人地址： 2000 Westchester Avenue White Plains, New York 10650 US
- 代理机构： Green, Mark Charles
- 优先权： US150919 19931112
- 主分类号： C07C29/132
- IPC分类号： C07C29/132 ; C07C29/88
摘要：
A method for preparing tertiary butyl alcohol wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium and gold supported on alumina, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.
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