发明授权
- 专利标题: ETHYLENE CONVERSION PROCESS
- 专利标题(中): 程序履行乙烯的
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申请号: EP95937977.7申请日: 1995-11-23
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公开(公告)号: EP0741682B1公开(公告)日: 1998-06-10
- 发明人: MAUNDERS, Barry, Martin
- 申请人: BP Chemicals Limited
- 申请人地址: Britannic House 1 Finsbury Circus London EC2M 7BA GB
- 专利权人: BP Chemicals Limited
- 当前专利权人: BP Chemicals Limited
- 当前专利权人地址: Britannic House 1 Finsbury Circus London EC2M 7BA GB
- 代理机构: Krishnan, Suryanarayana Kalyana
- 优先权: GB9424547 19941206
- 国际公布: WO9617811 19960613
- 主分类号: C07C11/02
- IPC分类号: C07C11/02 ; C07C2/10 ; C07C6/04 ; B01J23/755
摘要:
This invention relates to a process for converting ethylene to a mixture of 1-olefins by (a) feeding ethylene through an oligomerization catalyst bed to form an oligomer predominating in C2-C6 olefins and (b) feeding the oligomer, optionally admixed with fresh ethylene, containing at least 50 % by volume ethylene, through a metathesis catalyst bed to form a product predominating in C2-C6 1-olefins. Steps (a) and (b) can be carried out sequentially and in a single reactor under the same conditions of reaction temperature and pressure. This mitigates the perceived disadvantages of low activity and low conversions of relatively inexpensive oligomerization catalysts and forms oligomer having the desired distribution of 1-olefin components for use as comonomer in a polyolefin process.
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