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EP0748824A1 High stereoregular polypropylenes 无效
Hochstereospezifisches聚丙烯

High stereoregular polypropylenes
摘要:
A high stereoregular polypropylene characterized in that

(a) an isotactic pentad (m m m m) is 0.950 to 0.995,
(b) a syndiotactic pentad (r r r r) is 0 to 0.01,
(c) a different bond due to 2,1- and 1,3-insertions of propylene monomer is 0 to 0.3 mol%,
(d) an absence of a terminal double bond is confirmed,
(e) a weight average molecular weight (Mw) is 50,000 to 1,000,000 and
(f) a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight (Mn) is 1.5 to 3.8, (a) to (d) being determined from 13 C NMR spectra.
The high stereoregular polypropylenes have narrow molecular weight distributions and high melting points, which exhibit very high tenacity, high-temperature rigidity, heat resistance and good molding properties when used as molding materials.
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