发明授权
- 专利标题: METAL LIGAND CONTAINING BLEACHING COMPOSITIONS
- 专利标题(中): 金属配体含漂白组合物
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申请号: EP97934248.2申请日: 1997-07-22
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公开(公告)号: EP0923635B1公开(公告)日: 2003-02-26
- 发明人: COLLINS, Terrence, J. , HORWITZ, Colin, P.
- 申请人: CARNEGIE MELLON UNIVERSITY
- 申请人地址: 5000 Forbes Avenue Pittsburgh Pennsylvania 15213 US
- 专利权人: CARNEGIE MELLON UNIVERSITY
- 当前专利权人: CARNEGIE MELLON UNIVERSITY
- 当前专利权人地址: 5000 Forbes Avenue Pittsburgh Pennsylvania 15213 US
- 代理机构: Frankland, Nigel Howard
- 优先权: US684670 19960722; US804776 19970224
- 国际公布: WO98003626 19980129
- 主分类号: C11D3/39
- IPC分类号: C11D3/39 ; C07D257/02 ; C07D257/10 ; D21C9/16
摘要:
The invention provides a novel composition for bleaching cellulose based materials, such as wood pulp and paper which includes using an effective amount of a source of an oxidant and an oxidatively stable bleach activator having structure (I) wherein Y1, Y3 and Y4 each represents a bridging group having zero, one, two or three carbon containing nodes for substitution, and Y2 is a bridging group having at least one carbon containing node for substitution. Each node contains a C(R), C(R1)(R2), or a C(R)2 unit. Each R may be H, alkyl, cycloalkyl, cylcoalkenyl, alkenyl, aryl, alkynyl, alkylaryl, halogen, alkoxy, or phenoxy, CH2CF3, CF3 and combinations thereof, or form a substituted or unsubstituted benzene ring, or together with a paired R substituent bound to the same carbon atom form a cycloalkyl or cycloalkenyl ring; M is a transition metal; Q is any counterion; and L is any labile ligand.
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