发明公开
EP0961791A1 VERFAHREN UND KATALYSATOR ZUR HERSTELLUNG VON MITTEL- BIS ULTRA HOCHMOLEKULAREN POLYOLEFINEN 失效
工艺及催化剂的中到超高分子量聚烯烃的生产

VERFAHREN UND KATALYSATOR ZUR HERSTELLUNG VON MITTEL- BIS ULTRA HOCHMOLEKULAREN POLYOLEFINEN
摘要:
The invention relates to a method for producing polyolefins of medium to ultra-high molecular weight by homo- or copolymerization of olefins, specifically ethylene, with other alpha-olefins in the presence of a metallocene-type mixed Ziegler-Natta-catalyst placed onto an organic polymer material for producing shaped bodies, for example by extrusion, injection moulding, film blowing, sinter pressing or ram extrusion. According to the invention the catalyst contains as organic polymer material a partly chloromethylated styrene-divinyl benzene copolymer, a complex compound placed onto same containing Mg, Al and transition metals of the fourth subgroup, as well as reaction products of the latter with other organic compounds and transition metals of the fourth subgroup.
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