发明公开
- 专利标题: FLUOROCHEMICAL COMPOSITION COMPRISING A POLYURETHANE COMPRISING A POLYURETHANE HAVING A FLUOROCHEMICAL OLIGOMER AND A HYDROPHILIC SEGMENT TO IMPART STAIN RELEASE PROPERTIES TO A SUBSTRATE
- 专利标题(中): ON用化学FLUOR低聚物和亲水性链段的含氟化学组成聚氨酯基底除斑PROPERTIES贷款
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申请号: EP98922268.2申请日: 1998-05-14
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公开(公告)号: EP0981560A1公开(公告)日: 2000-03-01
- 发明人: ALLEWAERT, Kathy, E., M., L., A. , VANDER ELST, Pierre, J.
- 申请人: MINNESOTA MINING AND MANUFACTURING COMPANY
- 申请人地址: 3M Center,P.O. Box 33427 St. Paul,Minnesota 55133-3427 US
- 专利权人: MINNESOTA MINING AND MANUFACTURING COMPANY
- 当前专利权人: MINNESOTA MINING AND MANUFACTURING COMPANY
- 当前专利权人地址: 3M Center,P.O. Box 33427 St. Paul,Minnesota 55133-3427 US
- 代理机构: Voortmans, Gilbert J.L.
- 优先权: EP97201388 19970514
- 国际公布: WO9851723 19981119
- 主分类号: C08G18/28
- IPC分类号: C08G18/28 ; C08G18/62 ; D06M15/576 ; D06M13/428
摘要:
A method for preparing a fluorochemical composition comprising a polyurethane by reacting: (A) fluorochemical oligomer of formula (I): MfmMn-Q1-T1, wherein: MfmMn represents fluorochemical oligomer comprising m units derived from fluorinated monomer and n units derived from fluorine-free monomer and wherein the fluorinated monomers and fluorine-free monomers may be the same or different; m represents a value of 2 to 40; n represents a value of 0 to 20; T1 is -OH or -NH¿2?; Q?1 and T1¿ together represent the organic residue obtained by removing a hydrogen atom from a chain transfer agent that is functionalized with T1; (B) difunctional compound capable of reacting with an isocyanate; (C) monofunctional compound capable of reacting with an isocyanate and comprising a poly(oxyalkylene) group with (D) triisocyanate. Substrates treated with fluorochemical compositions prepared according to the method, have good stain release properties, particularly for oily stains and water based stains such as wine, tea and coffee.
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