发明公开
- 专利标题: PROCESS TO PRODUCE BIMODAL POLYOLEFINS WITH METALLOCENE CATALYSTS USING TWO REACTION ZONES
- 专利标题(中): 用于生产茂金属双峰聚烯烃在两个反应区
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申请号: EP98929381.6申请日: 1998-05-26
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公开(公告)号: EP0986588A1公开(公告)日: 2000-03-22
- 发明人: RAZAVI, Abbas , DEBRAS, Guy
- 申请人: FINA RESEARCH S.A.
- 申请人地址: Zone Industrielle C B-7181 Seneffe BE
- 专利权人: FINA RESEARCH S.A.
- 当前专利权人: FINA RESEARCH S.A.
- 当前专利权人地址: Zone Industrielle C B-7181 Seneffe BE
- 优先权: EP97108490 19970526
- 国际公布: WO9854232 19981203
- 主分类号: C08F10/02
- IPC分类号: C08F10/02 ; C08F297/08 ; C08F4/645 ; C08L23/08
摘要:
A process for the preparation of polyolefins having a bi- or multimodal molecular weight distribution which comprises: (i) contacting olefin monomer and a first co-reactant with a catalyst system in a first reaction zone under first polymerisation conditions to produce a product comprising a first polyolefin having a first molecular weight and distribution; and (ii) contacting olefin monomer and a second co-reactant with a catalyst system in a second reaction zone under second polymerisation conditions to produce a second polyolefin having a second molecular weight distribution different from the first molecular weight distribution; wherein the first and second polyolefins are mixed together, wherein one of the co-reactants is hydrogen and the other is a comonomer selected from butene, methylpentene, hexene or octene, and wherein each catalyst system comprises (a) a metallocene catalyst component comprising a bis tetrahydroindenyl compound of the general formula (IndH4)2R''MQ2 in which each Ind is the same or different and is indenyl or substituted indenyl, R'' is a bridge which comprises a C1-C4 alkylene radical, a dialkyl germanium or silicon or siloxane, or an alkyl phosphine or amine radical, which bridge is substituted or unsubstituted, M is a Group IV metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen; and (b) a cocatalyst which activates the catalyst component.
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