发明公开
EP1117709A1 PRODUCTION OF MULTIMODAL POLYETHYLENE 有权
多型聚乙烯的生产

  • 专利标题: PRODUCTION OF MULTIMODAL POLYETHYLENE
  • 专利标题(中): 多型聚乙烯的生产
  • 申请号: EP99950551.4
    申请日: 1999-09-24
  • 公开(公告)号: EP1117709A1
    公开(公告)日: 2001-07-25
  • 发明人: DEBRAS, GuyRAZAVI, AbbasMICHEL, Jacques
  • 申请人: FINA RESEARCH S.A.
  • 申请人地址: Zone Industrielle C 7181 Seneffe (Feluy) BE
  • 专利权人: FINA RESEARCH S.A.
  • 当前专利权人: FINA RESEARCH S.A.
  • 当前专利权人地址: Zone Industrielle C 7181 Seneffe (Feluy) BE
  • 优先权: EP98118190 19980925; EP98123826 19981215
  • 国际公布: WO0018814 20000406
  • 主分类号: C08F210/16
  • IPC分类号: C08F210/16 C08L23/04 C08F4/64
PRODUCTION OF MULTIMODAL POLYETHYLENE
摘要:
A process for the preparation of polyethylene resins having a multimodal molecular weight distribution which comprises: (i) contacting ethylene monomer and a comonomer comprising an alpha-olefin having from 3 to 10 carbon atoms with a first catalyst system in a first reactor under first polymerisation conditions to produce a first polyethylene having a first molecular weight, an HLMI of not more than 0.5 g/10 min and a first density of not more than 0.925 g/ml and the first catalyst system comprising: (a) a metallocene catalyst comprising a bis tetrahydroindenyl compound of the general formula: (IndH4)2R'MQ2 in which each Ind is the same or different and is indenyl or substituted indenyl, R' is a bridge which comprises a C1-C20 alkylene radical, a dialkyl germanium or silicon or siloxane, or an alkyl phosphine or amine radical, which bridge is substituted or unsubstituted; M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen; and (b) a cocatalyst which activates the catalyst component; (ii) providing a second polyethylene having a second lower molecular weight and second higher density than the first polyethylene, the second polyethylene having been produced using a catalyst other than the bis tetrahydroindenyl compound; and (iii) mixing together the first and second polyethylenes to form a polyethylene resin having a multimodal molecular weight distribution.
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