发明公开
EP1227368A2 Multicolor photographic element with improved latent image keeping
审中-公开
Photographische Mehrfarbelemente mit verbesserter Latentbildbeibehaltung
- 专利标题: Multicolor photographic element with improved latent image keeping
- 专利标题(中): Photographische Mehrfarbelemente mit verbesserter Latentbildbeibehaltung
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申请号: EP01205077.9申请日: 2001-12-24
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公开(公告)号: EP1227368A2公开(公告)日: 2002-07-31
- 发明人: Johnston, Sharon Gould , Muenter, Annabel Adams , Szatynski, Steven Patrick , Lenhard, Jerome Robert
- 申请人: EASTMAN KODAK COMPANY
- 申请人地址: 343 State Street Rochester, New York 14650 US
- 专利权人: EASTMAN KODAK COMPANY
- 当前专利权人: EASTMAN KODAK COMPANY
- 当前专利权人地址: 343 State Street Rochester, New York 14650 US
- 代理机构: Parent, Yves
- 优先权: US755419 20010105
- 主分类号: G03C7/30
- IPC分类号: G03C7/30
摘要:
This invention comprises multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said red-sensitive or green-sensitive layers comprises a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y';
wherein the speed gain deriving from addition of said compound to said layer is less than or equal to 0.05 log sensitivity units and wherein
X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is present in the emulsion layer, and wherein:
1) X-Y' has an oxidation potential between 0 and about 1.4 V;
2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X • and the leaving fragment Y'; and
3) the radical X • has an oxidation potential ≤-0.7V.
wherein the speed gain deriving from addition of said compound to said layer is less than or equal to 0.05 log sensitivity units and wherein
X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is present in the emulsion layer, and wherein:
1) X-Y' has an oxidation potential between 0 and about 1.4 V;
2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X • and the leaving fragment Y'; and
3) the radical X • has an oxidation potential ≤-0.7V.
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