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EP1238988A1 Perfluorodiacylperoxides as polymerization initiators 有权
全氟二羰基过氧化物聚合反应

Perfluorodiacylperoxides as polymerization initiators
摘要:
Perfluorodiacylperoxides having the following structures:
wherein:

when R f is F, R f' , R f'' are both -CF 3 ;
when R f is -CF 3 , R f' ,R f'' are C 1 -C 3 linear or branched perfluoro-oxyalkyl groups;
said perfluorodiacylperoxides being such as to meet the following proviso: the thermal decomposition constants K d (sec -1 ) in the presence of water do not undergo substantial variations with respect to the thermal decomposition constants in absence of water.
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