发明公开
EP1299449A1 VERBESSERTES VERFAHREN ZUR EINSTUFIGEN HERSTELLUNG VON POLYTETRAHYDROFURAN UND TETRAHYDROFURAN-COPOLYMEREN
审中-公开
改进方法聚四氢呋喃和四氢呋喃的共聚物的制备阶段
- 专利标题: VERBESSERTES VERFAHREN ZUR EINSTUFIGEN HERSTELLUNG VON POLYTETRAHYDROFURAN UND TETRAHYDROFURAN-COPOLYMEREN
- 专利标题(英): Improved method for the single-step production of polytetrahydrofuran and tetrahydrofuran copolymers
- 专利标题(中): 改进方法聚四氢呋喃和四氢呋喃的共聚物的制备阶段
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申请号: EP01945325.7申请日: 2001-06-29
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公开(公告)号: EP1299449A1公开(公告)日: 2003-04-09
- 发明人: BOHNER, Gerd , DOMSCHKE, Thomas , FISCHER, Rolf-Hartmuth , HAUBNER, Martin , SIGWART, Christoph , STEINBRENNER, Ulrich , TRAGUT, Christian
- 申请人: BASF AKTIENGESELLSCHAFT
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人地址: 67056 Ludwigshafen DE
- 优先权: DE10032266 20000703
- 国际公布: WO02002669 20020110
- 主分类号: C08G65/20
- IPC分类号: C08G65/20 ; C08G65/30
摘要:
The invention relates to a method for the single-step production of polytetrahydrofuran and/or tetrahydrofuran copolymers having an average molecular weight of 650 to 5000 daltons by polymerizing tetrahydrofuran on an acidic heterogeneous catalyst in the presence of at least one telogen and/or comonomer of the group of the alpha, omega diols, water, polytetrahydrofuran having a molecular weight of 200 to 700 daltons and/or of the cyclic ethers, characterized by a) removing the suspended and/or dissolved catalyst components and/or secondary products of the catalyst contained in the polymerization product, b) carrying out a separation in at least one distillation step from the resulting catalyst-free polymerization product to give a distillation product that contains the polymerization product and at least one tetrahydrofuran fraction, and returning at least part of the tetrahydrofuran fraction to the polymerization, and c) removing from the distillation residue of processing step b) the low-molecular polytetrahydrofuran and/or tetrahydrofuran copolymers that have an average molecular weight of 200 to 700 daltons, and obtaining a polytetrahydrofuran and/or tetrahydrofuran copolymer that has an average molecular weight of 650 to 5000 daltons.
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