发明公开
EP1305275A1 VERFAHREN ZUR HERSTELLUNG VON TERT.-BUTYLESTERN ALIPHATISCHER C 1?-C 4?-CARBONSÄUREN
有权
用于生产叔丁基酯脂族C 1 -C 4 - 碳ACIDS
- 专利标题: VERFAHREN ZUR HERSTELLUNG VON TERT.-BUTYLESTERN ALIPHATISCHER C 1?-C 4?-CARBONSÄUREN
- 专利标题(英): Method for producing tert-butyl esters of aliphatic c 1?-c 4?-carboxylic acids
- 专利标题(中): 用于生产叔丁基酯脂族C 1 -C 4 - 碳ACIDS
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申请号: EP01958028.1申请日: 2001-07-27
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公开(公告)号: EP1305275A1公开(公告)日: 2003-05-02
- 发明人: KROKER, Ruprecht , NESTLER, Gerhard , SCHMITT, Werner , SCHUMM, Winfried
- 申请人: BASF AKTIENGESELLSCHAFT
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人地址: 67056 Ludwigshafen DE
- 代理机构: Pohl, Michael, Dr.
- 优先权: DE10036959 20000728
- 国际公布: WO02010109 20020207
- 主分类号: C07C67/04
- IPC分类号: C07C67/04 ; C07C69/54 ; C07C69/14
摘要:
The invention relates to a method for the continuous production of the tert-butyl ester of an aliphatic C1-C4 carboxylic acid by reacting the carboxylic acid with isobutene in a liquid phase in the presence of an acid catalyst. The reaction is carried out in a reactor divided into several sections. The carboxylic acid, the iso-olefin and the catalyst are introduced into the first section of the reactor, the reaction mixture obtained is removed from the last section of the reactor, and the ester is extracted from said mixture. The reaction temperature in the reactor is controlled in such a way that it ranges from 10 to 40 °C and is highest in the first section of the reactor. The inventive method enables tertiary butyl esters of saturated and unsaturated C1-C4 carboxylic acids to be produced economically and in a technically simple and environmentally friendly manner.
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