发明公开
EP1305276A2 VERFAHREN ZUR HERSTELLUNG VON TERT.-C4-C8-ALKYLESTERN DER (METH)ACRYLSÄURE UND DARIN VERWANDTER FALLFILMVERDAMPFER
有权
用于生产(甲基)丙烯酸及其相关CASE膜蒸发器TERT C4-C8烷基酯
- 专利标题: VERFAHREN ZUR HERSTELLUNG VON TERT.-C4-C8-ALKYLESTERN DER (METH)ACRYLSÄURE UND DARIN VERWANDTER FALLFILMVERDAMPFER
- 专利标题(英): Method for producing tertiary c 4?-c 8?-alkyl esters of (meth)acryl acid
- 专利标题(中): 用于生产(甲基)丙烯酸及其相关CASE膜蒸发器TERT C4-C8烷基酯
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申请号: EP01971794.1申请日: 2001-07-27
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公开(公告)号: EP1305276A2公开(公告)日: 2003-05-02
- 发明人: KROKER, Ruprecht , NESTLER, Gerhard , SCHMITT, Werner , SCHUMM, Winfried
- 申请人: BASF AKTIENGESELLSCHAFT
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人地址: 67056 Ludwigshafen DE
- 代理机构: Thalhammer, Wolfgang, Dr.
- 优先权: DE10036958 20000728
- 国际公布: WO02010110 20020207
- 主分类号: C07C67/04
- IPC分类号: C07C67/04 ; C07C69/54 ; B01D1/06 ; B01D1/22 ; C07C67/54
摘要:
The invention relates to a method for producing a tertiary C4-C8 alkyl (meth)acrylate by reacting (meth)acryl acid with an olefin of formula (I), wherein R?1 and R2¿, which can be identical or different, represent methyl or ethyl and R3 represents H, methyl or ethyl, in a homogeneous phase in the presence of an acidic catalyst and extracting the tertiary C¿4?-C8 alkyl(meth)acrylate from the reaction mixture. According to the invention, the catalyst is separated as a residue in a two-stage distillation of the reaction mixture and the tertiary C4-C8 alkyl(meth)acrylate is extracted from the distillation. The inventive method permits the use of (meth)acryl acid that contains acetic acid. The risk of a breakdown of the ester and the polymerization of the (meth)acryl compounds is reduced. The invention also relates to a falling film evaporator comprising a cylindrical casing (2), a plurality of evaporation tubes (3) located in said casing (2), means (4) for supplying the liquid to be evaporated and means (5) for heating the evaporation tubes (3). Said evaporator is characterised in that at least one evaporation tube (3) has a closed head region (6), into which a supply line (7) for the liquid to be evaporated opens, said supply line (7) communicating with the means (4) for supplying the liquid to be evaporated.
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