发明公开
EP1306394A1 Ziegler-Natta catalyst for narrow to broad MWD of polyolefins, method of making, method of using, and polyolefins made therewith 有权
齐格勒 - 纳塔催化剂用于与窄到宽的分子量分布,制造工艺,使用方法聚烯烃; 和聚烯烃由此产生

  • 专利标题: Ziegler-Natta catalyst for narrow to broad MWD of polyolefins, method of making, method of using, and polyolefins made therewith
  • 专利标题(中): 齐格勒 - 纳塔催化剂用于与窄到宽的分子量分布,制造工艺,使用方法聚烯烃; 和聚烯烃由此产生
  • 申请号: EP01204067.1
    申请日: 2001-10-26
  • 公开(公告)号: EP1306394A1
    公开(公告)日: 2003-05-02
  • 发明人: Gray, Steven D.Coffy, Tim J.
  • 申请人: FINA TECHNOLOGY, INC.
  • 申请人地址: World Houston Plaza, 15710 JFK Blvd. Houston, Texas 77032 US
  • 专利权人: FINA TECHNOLOGY, INC.
  • 当前专利权人: FINA TECHNOLOGY, INC.
  • 当前专利权人地址: World Houston Plaza, 15710 JFK Blvd. Houston, Texas 77032 US
  • 代理机构: Detrait, Jean-Claude
  • 主分类号: C08F10/00
  • IPC分类号: C08F10/00
Ziegler-Natta catalyst for narrow to broad MWD of polyolefins, method of making, method of using, and polyolefins made therewith
摘要:
A Ziegler-Natta type catalyst providing for broadening of the MWD of resulting polyolefins polymerized using such catalyst, with such catalyst maintaining high activity and excellent fluff morphology. Generally, such catalyst is made by a) contacting a catalyst component with an organoaluminum preactivating agent, wherein the catalyst component is produced by a process comprising, i)contacting a soluble magnesium dialkoxide compound of the general formula Mg(OR'') 2 with a halogenating agent to form a reaction product A, ii) contacting reaction product A with a first halogenating/titanating agent to form reaction product B; and iii) contacting reaction product B with a second halogenating/titanating agent to form a catalyst component. The second halogenating/titanating agent comprises titanium tetrachloride, and step iii) comprises a ratio of titanium tetrachloride to magnesium compound in the range of about 0.1 to about 5. Catalyst components, catalysts, catalyst sytems, polyolefin polymers, and methods of forming each are disclosed.
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