发明公开
EP1318132A1 PROCESS FOR PRODUCING 1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE
有权
VERFAHREN ZUR HERSTELLUNG VON 1,1-BIS-(4-羟基苯基)-3,3,5-三甲基环己烷
- 专利标题: PROCESS FOR PRODUCING 1,1-BIS(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE
- 专利标题(中): VERFAHREN ZUR HERSTELLUNG VON 1,1-BIS-(4-羟基苯基)-3,3,5-三甲基环己烷
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申请号: EP00957100.1申请日: 2000-09-11
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公开(公告)号: EP1318132A1公开(公告)日: 2003-06-11
- 发明人: YAO, Kazuhiko, Honshu Chemical Industry Co., Ltd. , EKAWA, Kenji, Honshu Chemical Industry Co., Ltd. , ISOTA, Yoichiro Honshu Chemical Industry Co., Ltd. , NAKAGUCHI, Toru Honshu Chemical Industry Co., Ltd.
- 申请人: Honshu Chemical Industry Co. Ltd.
- 申请人地址: 1-1, Kyobashi 1-chome, Chuo-ku Tokyo 104-0031 JP
- 专利权人: Honshu Chemical Industry Co. Ltd.
- 当前专利权人: Honshu Chemical Industry Co. Ltd.
- 当前专利权人地址: 1-1, Kyobashi 1-chome, Chuo-ku Tokyo 104-0031 JP
- 代理机构: Cresswell, Thomas Anthony
- 国际公布: WO02022533 20020321
- 主分类号: C07C39/17
- IPC分类号: C07C39/17 ; C07C37/20 ; C07C37/84 ; C07B61/00
摘要:
A process for production of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane which comprises reacting phenol with 3,3,5-trimethylcyclohexanone in the presence of an acid catalyst, separating the resulting phenol adduct crystals of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane from the resulting reaction mixture, and removing the phenol from the phenol adduct crystals, wherein the phenol adduct crystals are dissolved in a crystallization solvent comprising an aromatic hydrocarbon solvent and water, crystallizing the crystals of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane out of the crystallization solvent, and collecting the crystals by filtration at a temperature of 40-60°C.
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