发明公开
EP1362838A2 A method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
有权
一种用于使用由其制备选定的聚合抑制剂和聚合物稳定乙烯基芳香族单体的方法
- 专利标题: A method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
- 专利标题(中): 一种用于使用由其制备选定的聚合抑制剂和聚合物稳定乙烯基芳香族单体的方法
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申请号: EP03076188.6申请日: 2003-04-22
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公开(公告)号: EP1362838A2公开(公告)日: 2003-11-19
- 发明人: Merrill, James T.
- 申请人: FINA TECHNOLOGY, INC.
- 申请人地址: World Houston Plaza, 15710 JFK Blvd. Houston, Texas 77032 US
- 专利权人: FINA TECHNOLOGY, INC.
- 当前专利权人: FINA TECHNOLOGY, INC.
- 当前专利权人地址: World Houston Plaza, 15710 JFK Blvd. Houston, Texas 77032 US
- 代理机构: Roufosse, Micheline
- 优先权: US139524 20020506
- 主分类号: C07C15/46
- IPC分类号: C07C15/46 ; C07C7/20 ; C08F112/08
摘要:
Disclosed is the observation that 7-aryl-quinone methides and 4-tert-butylcatechol, when used in combination in a vinyl aromatic monomer to inhibit polymerization, do not inhibit polymerization to the same extent as each would if used separately. Stated another way, a phenomenon has been observed that when these two compounds are used together, they can, to a large extent, render each other unable to inhibit polymerization in a vinyl aromatic monomer. Also disclosed are methods of preventing adverse results of this interaction when undesired and a method of using this interaction to prepare a reactive vinyl aromatic monomer having a concentration of 4-tert-butylcatechol that would otherwise inhibit polymerization. The invention is disclosed to be useful with the production and storage of any vinyl aromatic monomer and is disclosed to be particularly useful with the production and storage of styrene monomer.
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